Ruthenium Olefin Metathesis Catalysts Featuring Chelating Benzylidene-triazole Ligands

Authors

Allegra L. Liberman-Martin, Chapman UniversityFollow

Document Type

Article

Publication Date

8-17-2023

Abstract

In this issue of Chem Catalysis, Shi and co-workers describe the synthesis and olefin metathesis activity of ruthenium complexes with chelating benzylidene-triazole ligands. Catalyst decomposition is slow at up to 80°C, which enables challenging catalytic reactions, including cross-metathesis of trans-alkenes and macrocycle synthesis by dynamic covalent chemistry.

Comments

NOTICE: this is the author’s version of a work that was accepted for publication in Chem Catalysis. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Chem Catalysis, volume 3, issue 8, in 2023. https://doi.org/10.1016/j.checat.2023.100725

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Recommended Citation

Liberman-Martin, A. M. (2023). Ruthenium olefin metathesis catalysts featuring chelating benzylidene-triazole ligands. Chem Catalysis 3, 100725. https://doi.org/10.1016/j.checat.2023.100725

Copyright

Cell Press

Creative Commons License

This work is licensed under a Creative Commons Attribution-Noncommercial-No Derivative Works 4.0 License.