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  Loon Project Database

  Walter H. Piper

  Data collected since 1993 in Oneida County, Wisconsin, on the breeding and territorial behavior of the common loon, Gavia immer. This study population is marked with USGS metal bands and colored leg bands for individual identification. It includes many individuals banded as chicks, whose life histories are known thoroughly. Data are collected from April through August of most years on this migratory species.

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  "Probing the Transition State Region in Catalytic CO Oxidation on Ru" data files

  H. Öström, H. Öberg, H. Xin, Jerry L. LaRue, M. Beye, M. Dell'Angela, J. Gladh, M. L. Ng, J. A. Sellberg, S. Kaya, G. Mercurio, D. Nordlund, W. F. Schlotter, A. Föhlisch, M. Wolf, W. Wurth, M. Persson, J. K. Nørskov, F. Abild-Pedersen, H. Ogasawara, L. G. M. Pettersson, and A. Nilsson

  Femtosecond x-ray laser pulses are used to probe the CO oxidation reaction on Ru initiated by an optical laser pulse. On a timescale of a few hundred femtoseconds, the optical laser pulse excites motions of CO and O on the surface allowing the reactants to collide and, with a transient close to a picosecond (ps), new electronic states appear in the O K-edge x-ray absorption spectrum. Density functional theory calculations indicate that these result from changes in the adsorption site and bond-formation between CO and O with a distribution of OC—O bond lengths close to the transition state (TS). After 1 ps 10 % of the CO populate the TS region, which is consistent with predictions based on a quantum oscillator model.