Low-valent main group compounds have reactivity patterns and properties reminiscent of transition metals. While divalent carbon compounds such as carbenes are widely studied ligands and organocatalysts, zerovalent carbon species have received considerably less attention. This perspective highlights the properties and reactivity of zerovalent carbon compounds, focusing on their first applications as organocatalysts for small molecule reduction and polymerization reactions.
Liberman-Martin, A. L. (2023). The emergence of zerovalent carbon compounds from structural curiosities to organocatalysts. Cell Reports Physical Science, 4, 101519. https://doi.org/10.1016/j.xcrp.2023.101519
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